Oxidation behavior of AlN/CrN multilayered hard coatings
نویسندگان
چکیده
We report on the oxidation behavior of AlN/CrN multilayers at 900 °C, deposited by radio frequency magnetron sputtering. It is shown that oxidation in this system is controlled by diffusion of Cr towards the surface and formation of Cr2O3. Cr diffusion is found to mainly occur along grain boundaries. Thus, coherent cubic AlN/CrN multilayer regions with coarse columnar grain structures are found to be oxidation resistant, whereas regions decomposed into hexagonal AlN/cubic CrN are prone to oxidation.
منابع مشابه
Temperature activated self-lubrication in CrN/Mo2N nanolayer coatings
a r t i c l e i n f o Keywords: Lubricous oxides Hard coatings Lubricious oxides High temperature lubrication High temperature friction Temperature activated lubrication Multilayer coatings CrN/Mo 2 N In-situ lubrication Nanolayers Multilayered coatings Tool coatings Self lubrication Multi-layers Magnetron Sputtering Reactive sputtering CrN Mo 2 N CrN/Mo 2 N multilayers were deposited and TEM, ...
متن کاملEnhanced Corrosion Resistance of PVD-CrN Coatings by ALD Sealing Layers
Multilayered hard coatings with a CrN matrix and an Al2O3, TiO2, or nanolaminate-Al2O3/TiO2 sealing layer were designed by a hybrid deposition process combined with physical vapor deposition (PVD) and atomic layer deposition (ALD). The strategy was to utilize ALD thin films as pinhole-free barriers to seal the intrinsic defects to protect the CrN matrix. The influences of the different sealing ...
متن کاملStudy of multilayer and multi-component coatings deposited using cathodic Arc technique on H-13 hot work steel for die-casting applications
Die casting process is used since long, but even today problems like erosion, corrosion, soldering and sticking affect die life. These dies undergo thermal cyclic loads from 70 oC to 600 oC during processing. Physical Vapor Deposition (PVD) hard coating can play an important role in such extreme applications. In the present work, we report the use of Chromium based multila...
متن کاملMultilayered and nanolayered hard nitride thin films for a better yield in micro machining
TiN/AlTiN ; TiN/CrN and CrN/AlTiN multilayer coatings have been deposited by the cathodic arc evaporation technique. The period is in the range 7 – 200 nm for a total thichness of 3 μm. The period’s control of the nanoscaled hard films is achieved, a priori, by way of a simple geometrical calculation and, a posteriori, via both X-ray diffraction and transmission electron microscopy on cross-sec...
متن کاملEffect of Annealing Temperature on the Water Contact Angle of PVD Hard Coatings
Various PVD (physical vapor deposition) hard coatings including nitrides and metal-doped diamond-like carbons (Me-DLC) were applied in plastic injection and die-casting molds to improve wear resistance and reduce sticking. In this study, nitrides hcp-AlN (hexagonal close-packed AlN), Cr₂N, (CrAl)₂N) and Me-DLC (Si-DLC and Cr-DLC) coatings were prepared using a closed field unbalanced magnetron ...
متن کامل